133187-47-0Relevant academic research and scientific papers
Allenylsilanes fonctionnels: synthese regioselective par voie organoaluminique d'alcools alleniques trimethylsilyles α'- ou ω'-chlores
Mesnard, Danielle,Miginiac, Leone
, p. 299 - 309 (1991)
In many cases, the reaction between α- or ω-chloro carbonyl derivatives and organoaluminium compound prepared from Me3Si-CC-CH2Br is chemo- and regioselective: it affords, in a good yield, trimethylsilyl α-allenyl alcohols α'- or ω'-substituted by a chlorine atom; some of these functional alcohols have produced oxygenated heterocycles.
