133207-07-5Relevant academic research and scientific papers
IPy2BF4-mediated rearrangements of 1,2-difunctionalized compounds and olefins
Fananas, Francisco J.,Alvarez-Perez, Monica,Rodriguez, Felix
, p. 5938 - 5944 (2005)
Acetal derivatives are easily obtained from 1,2-difunctionalized compounds by a new reaction mediated by IPy2BF4 with a mechanism based on a 1,2-migration of aryl or alkyl groups. A new oxidative rearrangement reaction of olefins is also described. Moreover, when this metal-free protocol is applied to cyclic olefins, interesting ring-contraction reactions are observed. The new methodologies described here are a clean and efficient alternative to known strategies that make use of potentially toxic metallic complexes.
Rhenium complex-catalyzed Meinwald rearrangement reactions of oxiranes
Umeda, Rui,Muraki, Masahito,Nakamura, Yuudai,Tanaka, Tomoyuki,Kamiguchi, Kyohei,Nishiyama, Yutaka
supporting information, p. 2393 - 2395 (2017/05/29)
The Meinwald rearrangement reaction of oxiranes to the corresponding carbonyl compounds is efficiently catalyzed by the ReBr(CO)5 complex.
