133216-80-5

Basic information

• Product Name: ethyl 5,5-bis(4-chlorophenyl)-2-methyl-4,5-dihydrofuran-3-carboxylate
• Synonyms: ethyl 5,5-bis(4-chlorophenyl)-2-methyl-4,5-dihydrofuran-3-carboxylate
• CAS NO: 133216-80-5
• Molecular Weight: 377.267
• Mol File: 133216-80-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ethyl 5,5-bis(4-chlorophenyl)-2-methyl-4,5-dihydrofuran-3-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 5,5-bis(4-chlorophenyl)-2-methyl-4,5-dihydrofuran-3-carboxylate(133216-80-5)
• EPA Substance Registry System: ethyl 5,5-bis(4-chlorophenyl)-2-methyl-4,5-dihydrofuran-3-carboxylate(133216-80-5)

Safety Data

• Hazardous Substances Data: 133216-80-5(Hazardous Substances Data)

Upstream product

• 2642-81-1 1,1-bis(p-chlorophenyl)ethene 
• 141-97-9 ethyl acetoacetate 
• 80-06-8 chlorfenethol 
• 873-77-8 (4-chlorphenyl)magnesium bromide 
• 99-91-2 para-chloroacetophenone 

Relevant articles and documents

Advanced Synthesis of Dihydrofurans: Effect of Formic Acid on the Mn(III)-Based Oxidation

The Mn(III)-based oxidation of a tertiary alkylamine, such as nitrilotris(ethane-2,1-diyl) tris(3-oxobutanoate) (1) with 1,1-diphenylethene (2a), effectively proceeded in an acetic acid-formic acid mixed solvent to give nitrilotris(ethane-2,1-diyl) tris(2-methyl-5,5-diphenyl-4,5-dihydrofuran-3-carboxylate) (3). Other typical Mn(III)-based reactions of various β-diketo esters 4a-e, 2,4-pentanedione (6a), malonic acid (6b), and diethyl malonate (6c) with 1,1-diarylthenes 2a-d were also investigated in a similar acetic acid-formic acid mixed solvent and the reaction rate was accelerated and the product yield increased.