1332306-30-5Relevant academic research and scientific papers
Nonsymmetrical 3,4-dithienylmaleimides by cross-coupling reactions with indium organometallics: Synthesis and photochemical studies
Mosquera, ngeles,Frnandez, M. Isabel,Lopez, Moiss Canle,Sestelo, Jos Prez,Sarandeses, Luis A.
supporting information, p. 14524 - 14530 (2015/01/09)
The synthesis and photochemical study of novel nonsymmetrical 1,2-dithienylethenes (DTEs) with a maleimide bridge have been carried out. The synthetic approach to the DTEs was based on successive selective palladium-catalyzed cross-coupling reactions of 5-susbtituted-2-methyl-3-thiophenyl indium reagents with 3,4-dichloromaleimides. The required organoindium reagents were prepared from 2-methyl-3,5-dibromothiophene by a selective (C-5) coupling reaction with triorganoindium compounds (R3In) and subsequent metal-halogen exchange. The coupling reactions usually gave good yields and have a high atom economy with substoichiometric amounts of R3In. The results of photochemical studies show that these novel dithienylmaleimides undergo a photocyclization reaction upon irradiation in the UV region and a photocycloreversion after excitation in the visible region, thus they can be used as photochemical switches. ON-OFF operations can be repeated in successive cycles without appreciable loss of effectiveness in the process.
Photochemical control of a highly efficient addition reaction between electron-rich alkynes and tetracyanoethylene
Morimoto, Masakazu,Murata, Kimie,Michinobu, Tsuyoshi
supporting information; experimental part, p. 9819 - 9821 (2011/10/11)
The electron density of an alkyne moiety is enhanced by the photochromic ring closure of a diarylethene derivative, which allows the thermal addition reaction with a small π-acceptor, tetracyanoethylene, at room temperature.
