13324-18-0

Basic information

• Product Name: 3-ACETOXYBENZOPHENONE
• Synonyms: 3-ACETOXYBENZOPHENONE
• CAS NO: 13324-18-0
• Molecular Formula: C15H12O3
• Molecular Weight: 240.25
• Mol File: 13324-18-0.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 384.7°C at 760 mmHg
• Flash Point: 171.2°C
• Appearance: /
• Density: 1.17g/cm³
• Vapor Pressure: 4.01E-06mmHg at 25°C
• Refractive Index: 1.57
• CAS DataBase Reference: 3-ACETOXYBENZOPHENONE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-ACETOXYBENZOPHENONE(13324-18-0)
• EPA Substance Registry System: 3-ACETOXYBENZOPHENONE(13324-18-0)

Safety Data

• Hazardous Substances Data: 13324-18-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C15H12O3/c1-11(16)18-14-9-5-8-13(10-14)15(17)12-6-3-2-4-7-12/h2-10H,1H3

Upstream product

• 6304-89-8 3-acetoxybenzoic acid 
• 98-80-6 phenylboronic acid 

Relevant articles and documents

Palladium-catalyzed synthesis of aryl ketones from boronic acids and carboxylic acids activated in situ by pivalic anhydride

A new palladium-catalyzed cross-coupling reaction between arylboronic acids and mixed anhydrides, generated in situ from carboxylic acids and pivalic anhydride, is presented. Optimization of the new catalyst and the reaction conditions led to the development of a convenient one-pot ketone synthesis directly from carboxylic and boronic acids in the presence of different (phosphane)palladium complexes in wet THF at 60 °C. Systematic studies were performed to elucidate the reaction mechanism of this transformation. The scope and the limitations of the new process are demonstrated by the synthesis of 33 functionalized ketones. Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.

Palladium-Catalyzed Synthesis of Aryl Ketones from Boronic Acid and Carboxylic Acids or Anhysrides

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