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13324-20-4

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13324-20-4 Usage

Uses

Reactive Blue 4 (CAS# 13324-20-4) is an organic dye used in textiles. Reactive Blue 4 is water-soluble and a pollutant, and has been decolourized in water using microbial fuel cells. Dyes and metabolites.

Preparation

1-Amino-4-bromo-9,10-dioxo-9,10-dihydroanthracene-2-sulfonic acid and 2,4-Diaminobenzenesulfonic acid condensation, and ?2,4,6-Trichloro-1,3,5-triazine condensation and salting-out.

Properties and Applications

bright blue. Dark blue powder. The strong sulfuric acid for red brown, diluted into blue; In nitric acid to orange, no change after diluted. The dye water solution is blue, with 1 Moore sodium hydroxide solution is still blue, continue to join insurance powder and warm, turn dark red, plus a boric acid to red,. Mainly used for cotton, nylon, wool, silk and viscose yarn and fabric as the dyeing and printing, printing and dyeing directly. Structure and C.I.Reactive Blue 1 the same. Standard Light Fastness Oxygen bleaching Persperation Fastness Soaping Fading Stain Fading Stain Fading Stain ISO 6 3-4 4-5 4 (shallow, green ) 5 4(95℃) 4-5

Standard

Light Fastness

Fading

Stain

ISO

6

Check Digit Verification of cas no

The CAS Registry Mumber 13324-20-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,3,2 and 4 respectively; the second part has 2 digits, 2 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 13324-20:
(7*1)+(6*3)+(5*3)+(4*2)+(3*4)+(2*2)+(1*0)=64
64 % 10 = 4
So 13324-20-4 is a valid CAS Registry Number.
InChI:InChI=1/C23H14Cl2N6O8S2/c24-21-29-22(25)31-23(30-21)28-12-7-9(5-6-14(12)40(34,35)36)27-13-8-15(41(37,38)39)18(26)17-16(13)19(32)10-3-1-2-4-11(10)20(17)33/h1-8,27H,26H2,(H,34,35,36)(H,37,38,39)(H,28,29,30,31)

13324-20-4 Well-known Company Product Price

  • Brand
  • (Code)Product description
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  • Detail
  • Alfa Aesar

  • (A12911)  Reactive Blue 4, dye content ca 40%   

  • 13324-20-4

  • 25g

  • 493.0CNY

  • Detail
  • Alfa Aesar

  • (A12911)  Reactive Blue 4, dye content ca 40%   

  • 13324-20-4

  • 100g

  • 1344.0CNY

  • Detail

13324-20-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name Reactive Blue 4

1.2 Other means of identification

Product number -
Other names Procion Blue MX-R

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:13324-20-4 SDS

13324-20-4Synthetic route

1,3,5-trichloro-2,4,6-triazine
108-77-0

1,3,5-trichloro-2,4,6-triazine

1-amino-4-(3-amino-4-sulfophenylamino)anthraquinone-2-sulfonic acid
128-99-4

1-amino-4-(3-amino-4-sulfophenylamino)anthraquinone-2-sulfonic acid

Reactive blue 4
13324-20-4

Reactive blue 4

Conditions
ConditionsYield
With sodium hydroxide In water at 0℃; for 2.75h; pH=5;
sulfuric acid mono-[2-(3-ethylamino-benzenesulfonyl)-ethyl] ester
83574-63-4

sulfuric acid mono-[2-(3-ethylamino-benzenesulfonyl)-ethyl] ester

Reactive blue 4
13324-20-4

Reactive blue 4

C33H28ClN7O14S4

C33H28ClN7O14S4

Conditions
ConditionsYield
With sodium carbonate In water at 20℃; pH=7;
gadolinium(III) nitrate

gadolinium(III) nitrate

Reactive blue 4
13324-20-4

Reactive blue 4

Gd(3+)*C23H13N6O8S2Cl2(1-)*2NO3(1-)*2H2O=Gd(C23H13N6O8S2Cl2)(NO3)2*2H2O

Gd(3+)*C23H13N6O8S2Cl2(1-)*2NO3(1-)*2H2O=Gd(C23H13N6O8S2Cl2)(NO3)2*2H2O

Conditions
ConditionsYield
In water stirring for 2 h at 70 ° C;; cooling; sepn. of the product; filtration; elem. anal.;;
chromium(III) chloride
10025-73-7

chromium(III) chloride

Reactive blue 4
13324-20-4

Reactive blue 4

Cr(3+)*C23H13N6O8S2Cl2(1-)*2Cl(1-)*2H2O=Cr(C23H13N6O8S2Cl2)Cl2*2H2O

Cr(3+)*C23H13N6O8S2Cl2(1-)*2Cl(1-)*2H2O=Cr(C23H13N6O8S2Cl2)Cl2*2H2O

Conditions
ConditionsYield
In water stirring for 2 h at 70 ° C;; cooling; sepn. of the product; filtration; elem. anal.;;
Reactive blue 4
13324-20-4

Reactive blue 4

A

4-(methylamino)butyric acid
1119-48-8

4-(methylamino)butyric acid

B

2-hydroxy-1-nitropropane
3156-73-8

2-hydroxy-1-nitropropane

C

Phthalic acid dibutyl ester
84-74-2

Phthalic acid dibutyl ester

D

3-Hydroxybutyric acid
300-85-6, 625-71-8

3-Hydroxybutyric acid

E

para-methylbenzamide
619-55-6

para-methylbenzamide

Conditions
ConditionsYield
With sodium sulfate In water for 4h; Inert atmosphere; Electrochemical reaction;
Reactive blue 4
13324-20-4

Reactive blue 4

A

1-methyl-pyrrolidin-2-one
872-50-4

1-methyl-pyrrolidin-2-one

B

4-(methylamino)butyric acid
1119-48-8

4-(methylamino)butyric acid

C

Phthalic acid dibutyl ester
84-74-2

Phthalic acid dibutyl ester

Conditions
ConditionsYield
With sodium sulfate In water for 20h; Inert atmosphere; Electrochemical reaction;
Reactive blue 4
13324-20-4

Reactive blue 4

A

carbon dioxide
124-38-9

carbon dioxide

B

water
7732-18-5

water

Conditions
ConditionsYield
With γ-Fe2O3/N,Fe codoped TiO2 Reagent/catalyst; UV-irradiation;
benzyltriphenylphosphonium chloride
1100-88-5

benzyltriphenylphosphonium chloride

Reactive blue 4
13324-20-4

Reactive blue 4

2-(2-Aminoethoxy)ethanol
929-06-6

2-(2-Aminoethoxy)ethanol

C31H32N8O12S2(2-)*2C25H22P(1+)

C31H32N8O12S2(2-)*2C25H22P(1+)

Conditions
ConditionsYield
Stage #1: Reactive blue 4; 2-(2-Aminoethoxy)ethanol With sodium hydrogencarbonate In water at 80℃;
Stage #2: benzyltriphenylphosphonium chloride In water at 80℃; for 1h;
trihexyl(tetradecyl)phosphonium chloride
258864-54-9

trihexyl(tetradecyl)phosphonium chloride

Reactive blue 4
13324-20-4

Reactive blue 4

2-(2-Aminoethoxy)ethanol
929-06-6

2-(2-Aminoethoxy)ethanol

C31H32N8O12S2(2-)*2C32H68P(1+)

C31H32N8O12S2(2-)*2C32H68P(1+)

Conditions
ConditionsYield
Stage #1: Reactive blue 4; 2-(2-Aminoethoxy)ethanol With sodium hydrogencarbonate In water at 60℃;
Stage #2: trihexyl(tetradecyl)phosphonium chloride In water at 60℃; for 1h;

13324-20-4Related news

Efficient degradation of REACTIVE BLUE 4 (cas 13324-20-4) in carbon bed electrochemical reactor07/28/2019

A fixed bed electrochemical reactor comprising stainless steel cathode/granular activated carbon (GAC) bed//Carbon anode//GAC bed//stainless steel cathode configuration was fabricated and tested for degradation of Reactive Blue 4 aqueous solutions (RB4). On the basis of measured concentrations o...detailed

Elimination of REACTIVE BLUE 4 (cas 13324-20-4) from aqueous solutions using 3-aminopropyl triethoxysilane modified chitosan beads07/26/2019

The adsorption behavior of chitosan (CS) beads modified with 3-aminopropyl triethoxysilane (APTES) for the removal of reactive blue 4 (RB4) in batch studies has been investigated. The effects of modification conditions, such as the APTES concentration, temperature and reaction time on RB4 remova...detailed

Enhancing REACTIVE BLUE 4 (cas 13324-20-4) adsorption through chemical modification of chitosan with hexadecylamine and 3-aminopropyl triethoxysilane07/24/2019

The adsorption of dye on chitosan and its derivatives is considered as an alternative and environmentally friendly method. Nevertheless, chemical modification of chitosan can lead to a more suitable adsorbent. In this study, the adsorption performance of chemically modified chitosan beads using ...detailed

Synthesis of polymetallic nanoparticles from spent lithium-ion batteries and application in the removal of REACTIVE BLUE 4 (cas 13324-20-4) dye07/23/2019

In this study inedited polymetallic nanoparticles were synthesized from electronic wastes of spent lithium-ion batteries (PN-LIB) and applied in the removal of the dye reactive blue 4 (RB4). Initially, the extraction of metals from batteries was performed using HCl/HNO3 (3:1 v/v). Subsequently, ...detailed

Immobilization of peroxidase on polypyrrole-cellulose-graphene oxide nanocomposite via non-covalent interactions for the degradation of REACTIVE BLUE 4 (cas 13324-20-4) dye07/22/2019

In the present study novel polypyrrole-cellulose-graphene oxide nanocomposite (PCeGONC) was employed for the immobilization of ginger peroxidase (GP) via simple adsorption mechanism. Immobilization of enzyme on the obtained support resulted in enhancement of the enzyme activity. The recovery of ...detailed

Electrochemically-driven mineralization of REACTIVE BLUE 4 (cas 13324-20-4) cotton dye: On the role of in situ generated oxidants07/20/2019

Brazil is the fifth biggest global manufacturer of textiles and the fourth in cotton textile exports. Textile effluents contain organic dyes that are highly recalcitrant and difficult to oxidize by conventional physico-chemical and biological treatments. Mid-sized textile factories require relia...detailed

Chitosan hydrogel beads impregnated with hexadecylamine for improved REACTIVE BLUE 4 (cas 13324-20-4) adsorption07/21/2019

Adsorption performance of chitosan (CS) hydrogel beads was investigated after impregnation of CS with hexadecylamine (HDA) as a cationic surfactant, for the elimination of reactive blue 4 (RB4) from wastewater. The CS/HDA beads formed with 3.8% HDA were the most effective adsorbent. The adsorpti...detailed

Effective biotransformation and detoxification of anthraquinone dye REACTIVE BLUE 4 (cas 13324-20-4) by using aerobic bacterial granules07/19/2019

Treatment of textile wastewater containing anthraquinone dye is quite a huge challenge due to its complex aromatic structure and toxicity. Present study deals with the degradation and detoxification of anthraquinone dye reactive blue 4 using aerobic bacterial granules. Bacterial granules effecti...detailed

13324-20-4Relevant articles and documents

Discovery of potent competitive antagonists and positive modulators of the P2X2 receptor

Baqi, Younis,Hausmann, Ralf,Rosefort, Christiane,Rettinger, Jürgen,Schmalzing, Günther,Müller, Christa E.

, p. 817 - 830 (2011/04/15)

Evaluation and optimization of anthraquinone derivatives related to Reactive Blue 2 at P2X2 receptors yielded the first potent and selective P2X2 receptor antagonists. The compounds were tested for inhibition of ATP (10 μM) mediated currents in Xenopus oocytes expressing the rat P2X2 receptor. The most potent antagonists were sodium 1-amino-4-[3-(4,6-dichloro[1,3,5]triazine-2- ylamino)phenylamino]- 9,10-dioxo-9,10-dihydroanthracene-2-sulfonate (63, PSB-10211, IC50 8 6 nM) and disodium 1-amino- 4-[3-(4,6-dichloro[1,3, 5]triazine-2-ylamino)-4-sulfophenylamino]-9,10-dioxo-9,10-dihydroanthracene- 2-sulfonate (57, PSB-1011, IC50 79 nM). Compound 57 exhibited a competitive mechanism of action (pA2 7.49). It was >100-fold selective versus P2X4, P2X7, and several investigated P2Y receptor subtypes (P2Y24612); selectivity versus P2X1 and P2X3 receptors was moderate (>5-fold). Compound 57 was >13-fold more potent at the homomeric P2X2 than at the heteromeric P2X2/3 receptor. Several anthraquinone derivatives were found to act as positive modulators of ATP effects at P2X2 receptors, for example, sodium 1-amino-4-(3-phenoxyphenylamino)-9,10-dioxo-9,10- dihydroanthracene-2-sulfonate (51, PSB-10129, EC50 489 nM), which led to about a 3-fold increase in the ATP-elicited current.

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