1332458-53-3

Basic information

• Product Name: 3-ethyl-4-phenyl-2-(1-propen-2-yl)cyclopent-2-enone
• CAS NO: 1332458-53-3
• Molecular Weight: 226.318
• Mol File: 1332458-53-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-ethyl-4-phenyl-2-(1-propen-2-yl)cyclopent-2-enone(CAS DataBase Reference)
• NIST Chemistry Reference: 3-ethyl-4-phenyl-2-(1-propen-2-yl)cyclopent-2-enone(1332458-53-3)
• EPA Substance Registry System: 3-ethyl-4-phenyl-2-(1-propen-2-yl)cyclopent-2-enone(1332458-53-3)

Safety Data

• Hazardous Substances Data: 1332458-53-3(Hazardous Substances Data)

Upstream product

• 2757-04-2 phenyl cinnamate 
• 23056-94-2 2-methyl-1-hexen-3-yne 

Relevant articles and documents

Nickel-catalyzed formation of cyclopentenone derivatives via the unique cycloaddition of α,β-unsaturated phenyl esters with alkynes

Oxygen-containing organic compounds, such as ethers, carboxylates, and carbamates, have recently received increasing attention because of their newly discovered applications as electrophiles in cross-coupling reactions via transition metal-catalyzed C-O bond activation. However, no cycloaddition reaction involving their C-O bond activation has been demonstrated thus far. The present study developed a Ni(0)-catalyzed unique [3+2] cycloaddition reaction of α,β-unsaturated phenyl esters with alkynes in iPrOH to yield cyclopentenone derivatives.