1332505-48-2

Basic information

• Product Name: (E)-S-butyl 5-phenylpent-2-enethioate
• Synonyms: (E)-S-butyl 5-phenylpent-2-enethioate
• CAS NO: 1332505-48-2
• Molecular Weight: 248.389
• Mol File: 1332505-48-2.mol

Chemical Properties

• CAS DataBase Reference: (E)-S-butyl 5-phenylpent-2-enethioate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-S-butyl 5-phenylpent-2-enethioate(1332505-48-2)
• EPA Substance Registry System: (E)-S-butyl 5-phenylpent-2-enethioate(1332505-48-2)

Safety Data

• Hazardous Substances Data: 1332505-48-2(Hazardous Substances Data)

Upstream product

• 109-79-5 n-butanethiol 
• 24271-22-5 5-phenyl-2(E)-pentenoic acid 

Downstream Products

• 1332505-58-4 C₁₅H₂₂OS 

Relevant articles and documents

Ruthenium-catalyzed rearrangement of propargyl sulfoxides: Formation of α,β-unsaturated thioesters

Our previously developed strategy of generating ketene intermediates via Ru-catalyzed intramolecular oxidation of terminal alkynes is applied to propargyl sulfoxides. The reaction undergoes interesting further rearrangement upon the ketene generation to a

Conjugate reduction and reductive aldol cyclization of α,β- unsaturated thioesters catalyzed by (BDP)CuH

A conjugate reduction of α,β-unsaturated thioesters catalyzed by copper hydride using PMHS as stoichiometric reductant has been developed. 1,2-Bis(diphenylphosphino)benzene (BDP) was the most effective ligand for this reduction. Saturated thioesters could be produced in excellent yields when the substituent on the thiol is not sterically-demanding. This protocol was applied to induce the reductive aldol cyclization of keto-enethioates, which could offer β-hydroxythioesters in moderate to good yields.