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133256-59-4

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133256-59-4 Usage

General Description

1,5,9-Trimethyl-1,5,9-triazacyclododecane, also known as Me6TREN, is a cage-like organic compound with a chemical formula of C12H30N4. It belongs to the class of organic compounds known as triazacyclododecanes. Me6TREN is often used as a ligand for coordination complexes in the field of coordination chemistry, due to its ability to bind to metal ions and form stable complexes. It has also been studied for its potential applications in catalysis, drug delivery, and materials science. Me6TREN is generally considered to be non-toxic, but its specific properties and reactivity should be carefully considered and handled in a controlled manner.

Check Digit Verification of cas no

The CAS Registry Mumber 133256-59-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,3,2,5 and 6 respectively; the second part has 2 digits, 5 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 133256-59:
(8*1)+(7*3)+(6*3)+(5*2)+(4*5)+(3*6)+(2*5)+(1*9)=114
114 % 10 = 4
So 133256-59-4 is a valid CAS Registry Number.
InChI:InChI=1/C12H27N3/c1-13-7-4-9-14(2)11-6-12-15(3)10-5-8-13/h4-12H2,1-3H3

133256-59-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name 1,5,9-TRIMETHYL-1,5,9-TRIAZACYCLODODECANE

1.2 Other means of identification

Product number -
Other names N,N',N''-trimethyl-1,5,9-triazacyclododecane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:133256-59-4 SDS

133256-59-4Relevant articles and documents

Chloro(N,N′,N″-trimethyl-1,5,9-triazacyclododecane-κ 3N)zinc(II) hexafluorophosphate

Alcock, Nathaniel W.,Clase, Howard J.,Siltchenko, Svetlana,Rybak-Akimova, Elena,Busch, Daryle H.

, p. 338 - 340 (1998)

The preparation and crystal structure of [ZnCl(C12H27-N3)]PF6 are described. The Zn atom has a tetrahedral environment, coordinated to three N atoms of the triaza macrocyclic ligand and to one Cl- ion. The Zn - N distances are in the range 2.037 (1)-2.048 (1) A, with Zn - Cl 2.2010 (4) A.

Coordination to RMg+ and RZn+ cations

Tang, Hui

, p. 4810 - 4819 (2008/10/08)

Addition of a second coordinating agent (coord*) to a solution of RM(coord)+A- (R = ethyl or neopentyl, M = Zn or Mg, A- = 1,2,3,4-tetraphenylcyclopentadienyl) can provide equilibrium mixtures of these compounds, coord, and RM(coord*)+A-. This exchange with RMg(coord)+ requires the addition of a small amount of R2Mg, but added R2Zn is not necessary for exchanges with RZn(coord)+. The equilibrium constants provide information about the relative abilities of different coordinating agents to coordinate to RM+ and reveal significant differences between coordination to RMg+ and RZn+. Reactions of RM(coord)+ with R′2M (R = ethyl or neopentyl for RMg(coord)+ and ethyl, isopropyl, tert-butyl, neopentyl, or p-methylphenyl for RZn(coord)+) provide equilibrium mixtures of these components, R′M(coord)+, and R2M. The equilibrium constants provide information about the effect of R on stability. An X-ray structure of p-methylphenylzinc(2,5,8,11-tetramethyl-2,5,8,11-tetraazadodecane)+ shows that just three of the N atoms are coordinated to Zn. The effects of coord, R, and metal on RM(coord)+ stability are discussed, and the abilities of coordinating agents to coordinate to RM+, to slow allylic isomerization of (CH2 double bond CMeCH2)2Zn, and to convert R2Zn to RZn(coord)+ are compared.

Fragmentation During the Formic Acid/Formaldehyde (Eschweiler-Clarke) Methylation of Polyamines

Alder, Roger W.,Colclough, David,Mowlam, Rodney W.

, p. 7755 - 7758 (2007/10/02)

Eschweiler-Clarke methylations of both acyclic and cyclic polyamines can lead to methylation products of fragments of the original polyamine; thus 1,5,9,13-tetra-azatridecane yields 1,1,3,3-tetramethylpropanediamine exclusively and 1,5,9-triazacyclododecane gives 45 percent 1,5,9-trimethyl-1,5,9-triazacyclododecane and 45 percent 2,6,10-trimethyl-2,6,10-triazaundecane.

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