1332626-75-1Relevant academic research and scientific papers
Fascinating reactivity in gold catalysis: Synthesis of oxetenes through rare 4-exo-dig allene cyclization and infrequent β-hydride elimination
Alcaide, Benito,Almendros, Pedro,Del Campo, Teresa Martinez,Fernandez, Israel
, p. 9054 - 9056 (2011)
A novel reactivity in gold catalysis, namely the unusual preference for the 4-exo-dig cyclization in allene chemistry as well as the rare β-hydride elimination reaction, was uncovered starting from readily available allenols.
Platinum-catalyzed divergent reactivity of α-hydroxyallenes: Synthesis of dihydrofurans and α,β-unsaturated ketones
Alcaide, Benito,Almendros, Pedro,Fernandez, Israel,Campo, Teresa Martinez Del,Naranjo, Teresa
supporting information, p. 2681 - 2685 (2013/10/21)
α-Allenols were catalytically transformed into dihydrofurans in the presence of platinum dichloride. Notably, using platinum dichloride along with silver triflate as the catalytic system, α,β-unsaturated ketones were obtained. Therefore, the role of the s
