133268-42-5Relevant articles and documents
Stereocontrolled derivatization of 3-methoxyestra-1,3,5(10), n-tetraenes via lewis acid promoted prins reactions, (n=7; 8(9))
Kuenzer, Hermann,Sauer, Gerhard,Wiechert, Rudolf
, p. 743 - 746 (2007/10/02)
Steroidal olefins 1 and 3 undergo dimethylaluminum chloride-mediated Prins reactions with paraformaldehyde to furnish homoallylic alcohols 4 and 16 as major products. These ene reaction-type intermediates are converted into 6 and 17 by hydroxyl group-assi