133270-38-9

Basic information

• Product Name: {((C₆H₅)2PCH₃)3PdH}⁽¹⁺⁾*{HC(SO₂CF₃)2}^(1-)={((C₆H₅)2PCH₃)3PdH}{HC(SO₂CF₃)2}
• CAS NO: 133270-38-9
• Molecular Weight: 987.249
• Mol File: 133270-38-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {((C₆H₅)2PCH₃)3PdH}⁽¹⁺⁾*{HC(SO₂CF₃)2}^(1-)={((C₆H₅)2PCH₃)3PdH}{HC(SO₂CF₃)2}(CAS DataBase Reference)
• NIST Chemistry Reference: {((C₆H₅)2PCH₃)3PdH}⁽¹⁺⁾*{HC(SO₂CF₃)2}^(1-)={((C₆H₅)2PCH₃)3PdH}{HC(SO₂CF₃)2}(133270-38-9)
• EPA Substance Registry System: {((C₆H₅)2PCH₃)3PdH}⁽¹⁺⁾*{HC(SO₂CF₃)2}^(1-)={((C₆H₅)2PCH₃)3PdH}{HC(SO₂CF₃)2}(133270-38-9)

Safety Data

• Hazardous Substances Data: 133270-38-9(Hazardous Substances Data)

Upstream product

• 24981-80-4 tetrakis(methyldiphenylphosphine)palladium 
• 428-76-2 bis(trifluoromethanesulfonyl)methane 

Relevant articles and documents

Protonation of phosphine complexes of zerovalent nickel, palladium, platinum, and ruthenium with fluorocarbon acids

Protonation of phosphine complexes of zerovalent nickel, palladium, and platinum with H2C(SO2CF3)2 yields the HC(SO2CF3)2- salts of L3MH+ (L = Ph3P, Ph2PMe, Et3P; M = Ni, Pd, Pt). The cations in [(Ph3P)3PdH][HC(SO2CF3) 2], [(Ph2PMe)3PdH][HC(SO2CF3) 2], [(Ph3P)3NiH][HC(SO2CF3) 2], and [(Et3P)3NiH][HC(SO2CF3)2] are stereochemically nonrigid in CH2Cl2 solution, and thermodynamic parameters for the permutational processes are reported. Protonation of (Ph3P)3Pd(CO) affords fluxional [(Ph3P)4Pd2(μ-CO)(μ-H)][HC(SO 2CF3)2. Protonation of (Ph3P)2Ru(CO)3 yields [(Ph3P)2Ru(CO)3H][HC-(SO2CF 3)2]; crystal data: triclinic, P1; a = 13.261 (2), b = 14.216 (3), c = 12.912 (3) A?; α = 96.92 (3), β = 106.72 (3), γ = 67.24 (1)° Z = 2.