1332882-39-9

Basic information

• Product Name: 3,3,4-trimethyl-4-phenyl-1-pentene
• CAS NO: 1332882-39-9
• Molecular Weight: 188.313
• Mol File: 1332882-39-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3,3,4-trimethyl-4-phenyl-1-pentene(CAS DataBase Reference)
• NIST Chemistry Reference: 3,3,4-trimethyl-4-phenyl-1-pentene(1332882-39-9)
• EPA Substance Registry System: 3,3,4-trimethyl-4-phenyl-1-pentene(1332882-39-9)

Safety Data

• Hazardous Substances Data: 1332882-39-9(Hazardous Substances Data)

Upstream product

• 18293-99-7 Prenyltrimethylsilane 
• 3425-72-7 cumyl acetate 

Relevant articles and documents

Rhodium-catalyzed allylation of benzyl acetates with allylsilanes

Benzyl acetate reacted with allyltrimethylsilane to give an allylation product in the presence of a catalytic amount of the (cyclooctadiene)rhodium(I) chloride dimer {[Rh(cod)Cl]2}, sodium tetrakis[3,5- bis(trifluoromethyl)phenyl]borate (NaBARF), and triphenyl phosphite [P(OPh) 3] in refluxing 1,2-dichloroethane. Primary, secondary and tertiary benzyl acetates could be used for the reaction. Moreover, allylation of gem-benzyl acetate was possible with [Rh(cod)Cl]2, NaBARF, and P(OPh)3. Monoallylation and diallylation of gem-benzyl acetate could be controlled by altering the reaction conditions. Cationic rhodium species generated in situ act as a Lewis acid catalyst to give a benzyl carbocation by elimination of the acetoxy group from the benzylic carbon. Copyright