1332896-05-5Relevant articles and documents
Regioselective synthesis of β-aryl- and β-amino-substituted aliphatic esters by rhodium-catalyzed tandem double-bond migration/conjugate addition
Ohlmann, Dominik M.,Goossen, Lukas J.,Dierker, Markus
, p. 9508 - 9519 (2011)
Rhodium-phosphite catalysts were found to effectively mediate double-bond migrations within unsaturated esters. Once the double-bond is in conjugation with the carboxylate group, they also catalyze the Michael addition of carbon and nitrogen nucleophiles.