133295-19-9Relevant academic research and scientific papers
1,2,3-Triazoles from (Z)-β-(Formyloxy)vinyl Azides and Triethyl Phosphite
D'Andrea, Stan V.,Ghosh, Arun,Wang, Wuyi,Freeman, Jeremiah P.,Szmuszkovicz, Jacob
, p. 2680 - 2684 (1991)
(Z)-Sodium enolates of two α-azido ketones are O-formylated with Me3CCO2CHO in high yield to give isolable (Z)-β-(formyloxy)vinyl azides, which are converted to 1,2,3-triazoles under the influence of triethyl phosphite.A mechanism is proposed for triazole formation involving 1,5-electrocyclization of a vinyl phosphazide intermediate.
