1333071-61-6Relevant articles and documents
Catalytic intermolecular allyl-allyl cross-couplings between alcohols and boronates
Jimenez-Aquino, Agustin,Ferrer Flegeau, Emmanuel,Schneider, Uwe,Kobayashi, Shu
, p. 9456 - 9458 (2011)
We developed catalytic intermolecular C(sp3)-C(sp3) cross-couplings between various allyl alcohols and allyl boronates, which proceeded smoothly in the presence of nickel(0) under mild conditions to form 1,5-dienes with excellent linear- and γ-selectivity; the use of boronates proved to be crucial in terms of reactivity.