1333082-86-2Relevant academic research and scientific papers
Molecular complexity via C-H activation: A dehydrogenative Diels-Alder reaction
Stang, Erik M.,White, M. Christina
, p. 14892 - 14895 (2011)
Traditionally, C-H oxidation reactions install oxidized functionality onto a preformed molecular skeleton, resulting in a local molecular change. The use of C-H activation chemistry to construct complex molecular scaffolds is a new area with tremendous potential in synthesis. We report a Pd(II)/bis-sulfoxide- catalyzed dehydrogenative Diels-Alder reaction that converts simple terminal olefins into complex cycloadducts in a single operation.
