1333237-19-6

Upstream product

• 1333237-06-1 ((2S,3S)-3-((1R,2S,4S,5R,6R,9R,10S)-9-(benzyloxy)-4,10-bis(tert-butyldimethylsilyloxy)-1,2,5,6-tetrachloroundecyl)oxiran-2-yl)methanol 

Downstream Products

• 1333237-21-0 (((2S,3S)-3-((E)-3-((2S,3S)-3-((1R,4R,5S)-4-(benzyloxy)-5-(tert-butyldimethylsilyloxy)-1-chlorohexyl)oxiran-2-yl)-1-chloroprop-1-enyl)oxiran-2-yl)methoxy)(tert-butyl)dimethylsilane 
• 1333237-22-1 (1E,4S,5Z,9R,10S)-9-(benzyloxy)-10-(tert-butyldimethylsilyloxy)-1-((2S,3S)-3-((tert-butyldimethylsilyloxy)methyl)oxiran-2-yl)-1,5-dichloroundeca-1,5-dien-4-ol 
• 1333237-20-9 (1R,2S,4S,5R,6R,9R,10S)-9-(benzyloxy)-10-(tert-butyldimethylsilyloxy)-1-((2S,3S)-3-((tert-butyldimethylsilyloxy)methyl)oxiran-2-yl)-1,2,5,6-tetrachloroundecan-4-ol 

Relevant academic research and scientific papers

Synthesis of undecachlorosulfolipid A: Re-evaluation of the nominal structure

Halo-giant: The title compound at the left in the scheme was constructed by the synthesis and coupling of two stereochemically challenging fragments. A comparison of the NMR data of the synthetic material and the natural product indicates that the configuration had been misassigned in the latter. PT=5-(1-phenyltetrazolyl).