1333243-57-4Relevant academic research and scientific papers
Organophosphine/phosphite stabilized disilver(i) methanedisulphonates: Synthesis, solid state structures and their potential use as MOCVD precursors
Tao, Xian,Shen, Kecheng,Feng, Meng,Tang, Qingyun,Fang, Jiangtao,Wang, Yulong,Shen, Yingzhong
, p. 9250 - 9258 (2011)
New disilver(i) methanedisulphonate complexes [CH2(SO 3)2Ag2·Ln] (L = PPh 3; n = 2, 2a; n = 3, 2b; n = 4, 2c; n = 5, 2d; n = 6, 2e; L = P(OEt)3; n = 2, 2f; n = 4, 2g; n = 6, 2h) were prepared by the reaction of [CH2(SO3)2Ag2], which could be synthesized from methanedisulphonic acid and Ag2CO 3 in water, with triphenylphosphine or triethylphosphite in dichloromethane under a nitrogen atmosphere. The solid state structures of three complexes 2c, 2d and 2f were determined by single X-ray structure analysis. Hot-wall metal organic chemical vapor deposition (MOCVD) experiments were carried out at 395 °C, 420 °C and 450 °C using 2g as precursor for the deposition of silver films, respectively. The silver film with high purity obtained at 420 °C is dense and homogeneous, which is composed of many well isolated, granular particulates spreading all over the substrate surface.
