1333249-01-6Relevant academic research and scientific papers
Highly regioselective double hydrothiolation of terminal acetylenes with thiols catalyzed by palladium diacetate
Mitamura, Takenori,Daitou, Masayuki,Nomoto, Akihiro,Ogawa, Akiya
scheme or table, p. 413 - 415 (2011/05/16)
Treatment of terminal acetylenes 1 with two equivalents of thiols 2 in the presence of Pd(OAc)2 catalyst and H2O causes regioselective double hydrothiolation of 1, leading to the corresponding dithioketals 3 in moderate to good yields.
