133345-41-2Relevant academic research and scientific papers
Generation and aldol reaction of enolate anion adjacent to a η3-alln-mo(co)2 Cp moiety. Anew approach to the to the stereoselective synthesis of 1,3,5-triol and 2-vinyl-3-hydroxyl-tetrahydrofuran
Lin, Shie-Hsiung,Vong, Wen-Jung,Cheng, Cnih-Yi,Wang, Sue-Lein,Liu, Rai-Shung
, p. 7645 - 7648 (1990)
The enolate of CpMo(CO)2(syn-η3-1-C3H4COCH 3) generated with lithium diisopropylamide in THF undergoes diastereoselective aldol reaction with benzaldehyde; the alcohol thus formed has been utilized for stereoselective synthesis of 1.5-diphenyl-2-vinyl-pentan-1,3,5-triol and 2-vinyl-3-hydroxyl-5-phenyl-tetrahydrofuran.
