1333480-39-9

Upstream product

• 591-50-4 iodobenzene 
• 5464-86-8 2,2-diphenyl-1,3-propanediol 
• 947-91-1 Diphenylacetaldehyde 
• 1333480-34-4 3-((4-methoxybenzyl)oxy)-2,2,-diphenylpropan-1-ol 
• 1333480-33-3 2-(4-methoxyphenyl)-5,5-diphenyl-1,3-dioxane 
• 1333480-38-8 4-((4-methoxybenzyl)oxy)-1,3,3-triphenylbut-1-yne 
• 1333480-37-7 4-((4-methoxybenzyl)oxy)-3,3-diphenylbut-1-yne 
• 1333480-36-6 1,1-dibromo-4-((4-methoxybenzyl)oxy)-3,3-diphenylbut-1-ene 
• 1333480-35-5 3-((4-methoxybenzyl)oxy)-2,2,-diphenylpropanal 

Downstream Products

• 1333480-40-2 2,2,4-triphenylbut-3-ynal 
• 1333480-41-3 1,1',1''-(5-methylhex-4-en-1-yne-1,3,3-triyl)tribenzene 
• 1333480-47-9 1-methoxy-4-((E)-3,3,5-triphenylpent-1-en-4-yn-1-yl)benzene 
• 1333480-52-6 1,1',1''-pent-1-en-4-yne-3,3,5-triyltribenzene 

Relevant academic research and scientific papers

Rh(II)-Catalyzed Chemoselective Oxidative Amination and Nucleophilic Trapping of gem-Dimethyl Alkynyl-Tethered Sulfamates

A Rh(II)-catalyzed chemoselective oxidative amination and nucleophilic trapping of gem-dimethyl sulfamates has been presented. For 2,2-dimethyl-4-arylbut-3-yn-1-yl sulfamates, the reactions underwent a metallonitrene-initiated alkyne oxidation along with nucleophilic trapping of H2O upon oxidation, giving aroyl group containing heterocycles. For 2,2-dimethyl-4-arylpent-3-yn-1-yl sulfamates, the α-iminometal carbene intermediate was trapped by aryl group migration, delivering a styryl group containing heterocycles.

Platinum-catalyzed cycloisomerization of 1,4-enynes via 1,2-alkenyl rearrangement

The cycloisomerization of 1,4-enyne 1 in the presence of platinum(II) catalyst afforded 1,2,3-trisubstituted 1H-indene 2 and 20 in good to excellent yields. The reaction proceeded through an unprecedented 1,2-alkenyl rearrangement that afforded a novel re