1333557-80-4Relevant academic research and scientific papers
Rhodium-catalyzed, efficient deutero- and tritiosilylation of carbonyl compounds from hydrosilanes and deuterium or tritium
Rubio, Miguel,Campos, Jesuus,Carmona, Ernesto
, p. 5236 - 5239 (2011)
A cationic rhodium compound which is an active catalyst for both the hydrogen isotope exchange in hydrosilanes and the hydrosilylation of carbonyl compounds permits, in a one-flask, two-step procedure, efficient deutero- and tritiosilylations using SiEt3H under D2 (0.5 bar) or T2, at low catalyst loadings (0.1-0.5 mol %).
