133379-87-0Relevant academic research and scientific papers
Stereoselective rardical-mediated reduction and alkylation of α-halo esters
Guindon,Lavallee,Boisvert,Chabot,Delorme,Yoakim,Hall,Lemieux,Simoneau
, p. 27 - 30 (1991)
Radical-mediated reduction and alkylation of β-alkoxy-α-halo esters could be achieved with good stereoselection at low temperature.
Free radicals and Lewis acid. Chelation-controlled radical allylations of substituted α-halo- or α- phenylseleno-β-alkoxy esters. The endocyclic effect
Guerin,Chabot,Mackintosh,Ogilvie,Guindon
, p. 852 - 867 (2007/10/03)
The radical allylation of a series of (α-halo or (α-phenylseleno-β-alkoxy esters in the presence of MgBr2·OEt2 is reported and compared with analogous reactions under non-chelating conditions. The addition of MgBr2·OEtsub
