133382-20-4Relevant academic research and scientific papers
A Chiral Building Block with Bicyclooctanone Skeleton by the Reduction with Baker's Yeast
Kitahara, Takeshi,Miyake, Masahiro,Kido, Masaru,Mori, Kenji
, p. 775 - 782 (2007/10/02)
Preparation of functionalized bicyclooctan-2-one with high optical purity is described.Reduction of a bridged diketone 2 with baker's yeast gave an endo-hydroxyketone (+)-12 of 98.5-99.5percent e.e. in 91percent yield.X-ray crystallography of its (
