133382-89-5Relevant academic research and scientific papers
Preparation of new monomers aza-β3-aminoacids for solid-phase syntheses of aza-β3-peptides
Busnel, Olivier,Baudy-Floc'h, Miche?le
, p. 5767 - 5770 (2008/02/09)
The preparation of new Nβ-Fmoc-protected aza-β3-amino acids (aza-β3-aa) with proteinogenic side chains as well as their Nβ-Fmoc, Nβ-Cbz or Nβ-Boc aza-β3-amino esters (from Pro, Asn, Asp, Glu, Gln) by successive nucleophilic substitutions will be described.
Synthesis and spectroscopic properties of azaglutamine amino acid and peptide derivatives
Gray,Quibell,Jiang,Baggett
, p. 141 - 146 (2007/10/02)
tert-Butyl carbazate and Boc-amino acid hydrazides undergo a Michael addition with acrylamide to give substituted carbazates having the side-chain of glutamine on nitrogen. These carbazates may react with chloroformates to give protected azaglutamine esters, and N-activated amino acid esters to give azaglutamine peptides.
