1333986-05-2Relevant academic research and scientific papers
Synthesis, structure and optical properties of a zinc(II) tetrakis(phenylbutadiynyl)porphyrin
Yang, Liu-Tao,Wu, Di,Xiang, Hai-Feng,Zhou, Xiang-Ge,Deng, Yue-Fei
, p. 1987 - 1996 (2012)
A porphyrin complex, zinc(II) tetrakis(phenylbutadiynyl)porphyrin, is constructed through meso-substitution approach, which exhibits remarkable bathochromism in absorption and fluorescent spectrum. Both the Q bands in the absorption spectrum and the emission band are red-shifted to the saturated red region. The theoretical analysis showed that the meso-phenylbutadiynyl groups significantly extended the π-conjugation from the porphyrin core to the meso aryl groups.
