133408-50-1

Basic information

• Product Name: (E)-METOMINOSTROBIN
• Synonyms: (E)-METOMINOSTROBIN;(E)-Metominostrobin PESTANAL;Metominostrobin;methyl (e)-α-methoxyimino-n-methyl-2-phenoxyphenylacetamide;metominostrobin (bsi, pa iso);ssf-126;Metominofen;Metominostrobin [iso]
• CAS NO: 133408-50-1
• Molecular Formula: C₁₆H₁₆N₂O₃
• Molecular Weight: 284.31
• Mol File: 133408-50-1.mol
• Article Data: 15

Chemical Properties

• Melting Point: 88℃
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Appearance: /
• Density: 1.13g/cm³
• Refractive Index: 1.555
• Storage Temp.: 0-6°C
• PKA: 11.37±0.46(Predicted)
• CAS DataBase Reference: (E)-METOMINOSTROBIN(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-METOMINOSTROBIN(133408-50-1)
• EPA Substance Registry System: (E)-METOMINOSTROBIN(133408-50-1)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 133408-50-1(Hazardous Substances Data)

Usage

Uses

Different sources of media describe the Uses of 133408-50-1 differently. You can refer to the following data:
1. Agricultural chemical.
2. (E)-Metominostrobin is an amide and methoxyiminoacetamide strobilurin fungicide.

Definition

ChEBI: A monocarboxylic acid amide obtained by formal condensation of the carboxy group of (2E)-(methoxyimino)(2-phenoxyphenyl)acetic acid with the amino group of methylamine. Used for the control of Pyricularia oryzae on rice crops.

Hazard

Moderately toxic by ingestion.

InChI:InChI=1/C16H16N2O3/c1-17-16(19)15(18-20-2)13-10-6-7-11-14(13)21-12-8-4-3-5-9-12/h3-11H,1-2H3,(H,17,19)/b18-15-

Upstream product

• 74-88-4 methyl iodide 
• 101-84-8 diphenylether 
• 139995-83-8 α-methoxyimino-2-phenoxyphenylacetonitrile 
• 77-78-1 dimethyl sulfate 

Downstream Products

• 133429-62-6 (E)-N-methyl-2-[2-(4-isopropylphenoxy)phenyl]-2-methoxyiminoacetamide 
• 133408-65-8 (E)-N-methyl-2-[2-(4-t-butylphenoxy)phenyl]-2-methoxyiminoacetamide 
• 133408-63-6 (E)-N-methyl-2-[2-(4-bromophenoxy)phenyl]-2-methoxyiminoacetamide 
• 133408-62-5 (E)-N-methyl-2-[2-(4-chlorophenoxy)-phenyl]-2-methoxyiminoacetamide 
• 133408-56-7 (E)-N-methyl-2-(5-nitro-2-phenoxyphenyl)-2-methoxyiminoacetamide 

Relevant articles and documents

Synthetic method for (E)-2-methoximino-N-methyl-2-(2-phenoxyphenyl)acetamide

The invention discloses a synthetic method for (E)-2-methoximino-N-methyl-2-(2-phenoxyphenyl)acetamide. The synthetic method comprises the following steps: with diphenyl ether as a starting material,allowing the diphenyl ether to react with dimethyl oxalate so as to prepare an intermediate namely 2-(2-phenoxyphenyl)-2-methyl oxoacetate, then allowing the 2-(2-phenoxyphenyl)-2-methyl oxoacetate toreact with hydroxylamine so as to prepare an oxime compound, and subjecting the oxime compound to amination so as to prepare the (E)-2-methoximino-N-methyl-2-(2-phenoxyphenyl)acetamide. The preparation method provided by the invention has the advantages of cheap and easily-available raw materials, simple process, less three wastes, avoidance of using highly-toxic raw materials, applicability to industrial production, etc. The (E)-2-methoximino-N-methyl-2-(2-phenoxyphenyl)acetamide provided by the invention is a highly-efficient agricultural fungicide, and has strong prevention and treatment effects on diseases like rice blast, sheath blight, cucumber powdery mildew and downy mildew.

3-phenyl-pyrones

Novel 3-phenyl-pyrones of the formula in which A, D, X and Y are each as defined in the description, a process for preparing these substances and their use as pesticides, fungicides and herbicides.

Utilization of 3-phenyl-pyrones for pest control

3-Phenyl-pyrones of the formula in which x represents pyrid-2-yl and Y represents fluorine, or x represents 4-fluoro-phenyl and Y represents chlorine, are highly suitable for use as pesticides, fungicides and herbicides.