1334170-91-0Relevant academic research and scientific papers
Scaffolding catalysis: Expanding the repertoire of bifunctional catalysts
Tan, Kian L.,Sun, Xixi,Worthy, Amanda D.
, p. 321 - 325 (2012)
Inducing an intramolecular reaction is a powerful means of accelerating reactions. Though this mechanism of catalysis is common in enzymes, it is underutilized in synthetic catalysts. This article outlines our groups recent efforts to use reversible coval
Scaffolding catalysts: Highly enantioselective desymmetrization reactions
Sun, Xixi,Worthy, Amanda D.,Tan, Kian L.
supporting information; experimental part, p. 8167 - 8171 (2011/10/18)
Ex-changing places: A highly enantioselective desymmetrization of 1,2-diols has been developed in which the catalyst utilizes reversible covalent bonding to the substrate to achieve both high selectivity and rate acceleration (see scheme, PMP=pentalmethyl
