1334289-63-2Relevant academic research and scientific papers
Diverted domino reactivity in tertiary skipped diynes: A convenient access to polyfunctionalized cyclohexadienones and multivalent aromatic scaffolds
Tejedor, David,Lopez-Tosco, Sara,Gonzalez-Platas, Javier,Garcia-Tellado, Fernando
supporting information; experimental part, p. 9571 - 9575 (2011/10/05)
Diverting is the game! A new domino manifold has been implemented for the synthesis of cyclohexadienone-based scaffolds from tertiary skipped diynes and secondary amines. The manifold takes advantage of a new O-enolate-driven reactivity pattern discovered for these diynes. The scaffolds are conveniently transformed into the corresponding multivalent salicylate derivatives (see scheme).
