1334317-38-2Relevant academic research and scientific papers
Solid state π-π Stacking and higher order dimensional crystal packing, reactivity, and electrochemical behaviour of salphenazine actinide and transition metal complexes
Hardy,Eddy,Maynard,Gorden
, p. 14243 - 14251 (2016)
Condensation of a 2,3-diaminophenazine or 2,3-diamino-2-quinoxalinol with two equivalents of 3,5-ditertbutylsalicylaldehyde affords new Schiff base ligands. Here, we describe and compare the synthesis, UV-Vis, electrochemical, solution, and solid state behaviour of the free base, salphenazine ligand [LI], and M[LI] complexes, where M = UO2(vi), Cu(ii), VO(iv), Zn(ii), Co(ii), and Ni(ii). The change in π-overlap and π-stacking between molecules and long-range ordering of the solid-state structure is vastly different depending on the size and electronic character of the metal. A sterically constrained μ-oxo Fe(iii) dimer complex is also reported.
A partially water-soluble cationic Mn(III)-salphen complex for catalytic epoxidation
Abdolmaleki, Amir,Malek-Ahmadi, Saeed
, p. 1202 - 1206 (2011)
Synthesis and application of new cationic Mn(III)-salphen complexes for catalytic epoxidation of olefins to epoxides in a homogeneous reaction media have been reported. The experimental data showed that the cationic salphen is more active than its neutral form. The acceleration of the reaction rate is attributed to the phase-transfer capability of the built-in phenazinium salt of the Mn(III)-salphen catalyst.
