1334319-85-5

Basic information

• Product Name: (E)-ethyl 2-(2-(1-hydroxy-1,2,3,4-tetrahydronaphthalen-2-yl)hydrazono)-3-phenylpropanoate
• Synonyms: (E)-ethyl 2-(2-(1-hydroxy-1,2,3,4-tetrahydronaphthalen-2-yl)hydrazono)-3-phenylpropanoate
• CAS NO: 1334319-85-5
• Molecular Weight: 352.433
• Mol File: 1334319-85-5.mol

Chemical Properties

• CAS DataBase Reference: (E)-ethyl 2-(2-(1-hydroxy-1,2,3,4-tetrahydronaphthalen-2-yl)hydrazono)-3-phenylpropanoate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-ethyl 2-(2-(1-hydroxy-1,2,3,4-tetrahydronaphthalen-2-yl)hydrazono)-3-phenylpropanoate(1334319-85-5)
• EPA Substance Registry System: (E)-ethyl 2-(2-(1-hydroxy-1,2,3,4-tetrahydronaphthalen-2-yl)hydrazono)-3-phenylpropanoate(1334319-85-5)

Safety Data

• Hazardous Substances Data: 1334319-85-5(Hazardous Substances Data)

Upstream product

• 1334318-90-9 (S,E)-ethyl 2-(2-(1-oxo-1,2,3,4-tetrahydronaphthalen-2-yl)hydrazono)-3-phenylpropanoate 

Relevant articles and documents

New electrophilic addition of α-diazoesters with ketones for enantioselective C-N bond formation

α-Diazoesters were discovered to be good electrophiles in a catalytic asymmetric α-functionalization of ketones for the first time. This reaction also provided a direct and efficient method for C-N bond formation with excellent yields (up to 98%) and enantioselectivities (up to 99% ee) under mild conditions. The application of the electrophilicity of α-diazoesters opens up a novel way to access the diversity of diazo chemistry.