1334336-33-2Relevant academic research and scientific papers
Pyridinyl directed alkenylation with olefins via Rh(III)-catalyzed C-C bond cleavage of secondary arylmethanols
Li, Hu,Li, Yang,Zhang, Xi-Sha,Chen, Kang,Wang, Xin,Shi, Zhang-Jie
supporting information; experimental part, p. 15244 - 15247 (2011/11/05)
Novel C-C bond cleavage of secondary alcohols through Rh(III)-catalyzed β-carbon elimination directed by a pyridinyl group is reported. A five-membered rhodacycle is proposed as a key intermediate, which undergoes further alkenylation with various olefins. This novel transformation shows high efficiency along with excellent selectivity in mild conditions. A wide range of functionalities are compatible. This study offers a new strategy to carry out C-C bond activation.
