1334652-48-0

Basic information

• Product Name: 6-O-benzyl-3,4-anhydro-5a-carba-D-allal
• Synonyms: 6-O-benzyl-3,4-anhydro-5a-carba-D-allal
• CAS NO: 1334652-48-0
• Molecular Weight: 216.28
• Mol File: 1334652-48-0.mol

Chemical Properties

• CAS DataBase Reference: 6-O-benzyl-3,4-anhydro-5a-carba-D-allal(CAS DataBase Reference)
• NIST Chemistry Reference: 6-O-benzyl-3,4-anhydro-5a-carba-D-allal(1334652-48-0)
• EPA Substance Registry System: 6-O-benzyl-3,4-anhydro-5a-carba-D-allal(1334652-48-0)

Safety Data

• Hazardous Substances Data: 1334652-48-0(Hazardous Substances Data)

Upstream product

• 1334652-33-3 2-formyl-3,4-di-(p-methoxybenzyloxy)-3,4-dihydro-2H-pyran 
• 1334652-31-1 3,4-di-O-(p-methoxybenzyl)-6-O-(2-tetrahydropyranyl)-D-glucal 
• 1334652-30-0 6-O-benzyl-5a-carba-D-glucal 
• 1334652-34-4 6-O-benzyl-3,4-di-O-(p-methoxybenzyl)-5a-carba-D-glucal 
• 1334652-29-7 3,4-di-O-(p-methoxybenzyl)-5a-carba-D-glucal 
• 1334652-28-6 1,5-anhydro-di-O-(p-methoxybenzyl)-2,6,7-trideoxy-D-arabinohepta-1,6-dienitol 
• 1334652-32-2 3,4-di-O-(p-methoxybenzyl)-D-glucal 
• 1033614-25-3 6-O-(tetrahydropyran-2-yl)-D-glucal 

Downstream Products

• 1334652-39-9 C₂₁H₂₈O₃ 
• 1334652-40-2 C₂₁H₂₈O₃ 
• 1334652-41-3 C₂₁H₂₈O₃ 

Relevant articles and documents

Stereodivergent synthesis of diastereoisomeric carba analogs of glycal-derived vinyl epoxides: A new access to carbasugars

A convenient method for the stereoselective synthesis of diasteroisomeric vinyl epoxides (-)-2α and (-)-2β, the carba analogs of D-galactal and D-allal-derived vinyl epoxides 1αand 1β, has been elaborated starting from tri-O-acetyl-D-glucal. The key step of this synthesis is an application of the known Claisen thermal rearrangement of a glucal derivative, the vinyl allyl ether (+)-3b, which allows to switch the glycal structure into the corresponding carba analog scaffold. Epoxides (-)-2α and (-)-2β derive from the same synthetic intermediate, the trans diol (+)-5. Chirality, 2011. 2011 Wiley-Liss, Inc. Copyright