1334824-01-9Relevant articles and documents
Double Ci-H bond activation of C(sp3)H2 groups for the preparation of complexes with back-to-back bisimidazolinylidenes
Prades, Amparo,Poyatos, MacArena,Mata, Jose A.,Peris, Eduardo
, p. 7666 - 7669 (2011)
Two-headed carbenes: N-heterocyclic carbene complexes of rhodium and iridium were obtained by the double Ci-H activation of CH2 groups in N heterocycles (see structure: C gray, N blue, Cl green, Ir pink). The reaction constitutes a valuable approach to new carbene ligands with unprecedented architectures. Copyright