133489-00-6

Basic information

• Product Name: 1-(1-hexynyl)cyclohexan-1-yl methyl carbonate
• Synonyms: 1-(1-hexynyl)cyclohexan-1-yl methyl carbonate
• CAS NO: 133489-00-6
• Molecular Weight: 238.327
• Mol File: 133489-00-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(1-hexynyl)cyclohexan-1-yl methyl carbonate(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(1-hexynyl)cyclohexan-1-yl methyl carbonate(133489-00-6)
• EPA Substance Registry System: 1-(1-hexynyl)cyclohexan-1-yl methyl carbonate(133489-00-6)

Safety Data

• Hazardous Substances Data: 133489-00-6(Hazardous Substances Data)

Upstream product

• 15332-33-9 1-(hex-1-ynyl)cyclohexanol 
• 79-22-1 methyl chloroformate 
• 108-94-1 cyclohexanone 
• 693-02-7 hex-1-yne 

Downstream Products

• 133489-06-2 4-Cyclohexylidenemethylene-oct-2-yn-1-ol 
• 75031-51-5 (1-cyclohexylidenehex-1-en-2-yl)benzene 
• 20023-45-4 hex-1-enylidenecyclohexane 
• 1082069-26-8 4,4,5,5-tetramethyl-2-(2-butyl-1-cyclohexylidenethenyl-2-yl)-[1,3,2]dioxaborolane 

Relevant articles and documents

Borylation of propargylic substrates by bimetallic catalysis. Synthesis of allenyl, propargylic, and butadienyl bpin derivatives

Bimetallic Pd/Cu and Pd/Ag catalytic systems were used for borylation of propargylic alcohol derivatives. The substrate scope includes even terminal alkynes. The reactions proceed stererospecifically with formal S N2′ pathways to give allenyl boronates. Opening of propargyl epoxides leads to 1,2-diborylated butadienes probably via en allenylboronate intermediate.