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Asymmetric Synthesis of Chiral Phosphorus Co,pounds by Destructive-Selective Oxidation of P(III) Compounds by Means of Chiral Oxaziridines
Verfuerth, Uwe,Ugi, Ivar
, p. 1627 - 1634 (2007/10/02)
From camphor and fenchone chiral N-sulfonyloxaziridines (e.g. 7, 13) are available that are well-suited for the destructive-stereoselective oxidation of P(III) compounds 16.Optimum reagents and reaction conditions for this oxidation are determined by a systematic study.Chiral P(III) and P(V) compounds can thus be prepared from racemic P(III) derivatives. Key Words : Stereoselectivity, destructive / Phosphite oxidation / Oxaziridines, chiral
