1335136-61-2Relevant academic research and scientific papers
Palladium-Catalyzed Electrochemical C-H Alkylation of Arenes
Yang, Qi-Liang,Li, Chuan-Zeng,Zhang, Liang-Wei,Li, Yu-Yan,Tong, Xiaofeng,Wu, Xin-Yan,Mei, Tian-Sheng
supporting information, p. 1208 - 1212 (2018/10/20)
Palladium-catalyzed electrochemical C-H functionalization reactions have emerged as attractive tools for organic synthesis. This process offers an alternative to conventional methods that require harsh chemical oxidants. However, this electrolysis requires divided cells to avoid catalyst deactivation by cathodic reduction. Herein, we report the first example of palladium-catalyzed electrochemical C-H alkylation of arenes using undivided electrochemical cells in water, thereby providing a practical solution for the introduction of alkyl groups into arenes.
Expanding the scope of the Cu assisted Suzuki-Miyaura reaction
Crowley, Brendan M.,Potteiger, Craig M.,Deng, James Z.,Prier, Christopher K.,Paone, Daniel V.,Burgey, Christopher S.
supporting information; experimental part, p. 5055 - 5059 (2011/10/09)
Recent advances in the development of the copper facilitated Suzuki-Miyaura reaction are described. Improvements include expansion of substrate scope to include aryl chlorides and polyhalo aryl boronates. It was found that use of S-Phos and X-Phos could a
