1335231-34-9

Upstream product

• 1335231-33-8 Ge(2,6-iPr₂C₆H₃NC₇H₈P((NtBu)2SiMe₂))(C(N₂)P(N(iPr)2)2) 
• 1335231-31-6 GeCl(2,6-iPr₂C₆H₃NC₇H₈P((NtBu)2SiMe₂)) 
• 113533-26-9 [Bis(diisopropylamino)phosphino]diazomethane lithium salt 

Downstream Products

• 1335231-35-0 Ge(2,6-iPr₂C₆H₃NC₇H₈P((NtBu)2SiMe₂))(C(N(iPr)2)PN(iPr)2) 
• 1335231-36-1 Ge(2,6-iPr₂C₆H₃NC₇H₈P((NtBu)2SiMe₂)C(P(N(iPr)2)2)) 

Relevant academic research and scientific papers

Synthesis and reactivity of a phosphine-stabilized monogermanium analogue of alkynes

The synthesis of the first isolable C-phosphino-Ge-aminogermyne, stabilized by a phosphine ligand, has been achieved. X-ray diffraction analysis indicates a quite long Ge-C bond whose length is between that of a single and a double bond but consistent with the theoretically predicted values for a germyne bearing π-donating substituents. The isomerization of this germyne derivative affords a new stable N-heterocyclic germylene through migration of the original phosphine ligand from germanium to the carbon center.