1335243-50-9

Basic information

• Product Name: [(RhCl((CH₃)3CS(O)C₆H₄C(CH₂)C₆H₅))2]
• CAS NO: 1335243-50-9
• Molecular Weight: 845.561
• Mol File: 1335243-50-9.mol

Chemical Properties

• CAS DataBase Reference: [(RhCl((CH₃)3CS(O)C₆H₄C(CH₂)C₆H₅))2](CAS DataBase Reference)
• NIST Chemistry Reference: [(RhCl((CH₃)3CS(O)C₆H₄C(CH₂)C₆H₅))2](1335243-50-9)
• EPA Substance Registry System: [(RhCl((CH₃)3CS(O)C₆H₄C(CH₂)C₆H₅))2](1335243-50-9)

Safety Data

• Hazardous Substances Data: 1335243-50-9(Hazardous Substances Data)

Relevant articles and documents

Chiral sulfoxide-olefin ligands: Completely switchable stereoselectivity in rhodium-catalyzed asymmetric conjugate additions

Have it both ways: A novel class of chiral sulfoxide-olefin ligands was synthesized from a single chiral source. These ligands were evaluated in rhodium-catalyzed 1,4-additions of arylboronic acids to electron-deficient olefins, and remarkable olefin-directed reversal of stereoselectivity (up to >99 ee, R isomer; 98 ee, S isomer) was observed when the reversal ligand pair L1 (branched olefin) and L2 (linear olefin) were utilized (see scheme). Copyright