133548-33-1

Basic information

• Product Name: ((Z,Z)-cycloocta-1,5-diene){(R)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine)}rhodium(I) perchlorate
• CAS NO: 133548-33-1
• Molecular Weight: 893.158
• Mol File: 133548-33-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ((Z,Z)-cycloocta-1,5-diene){(R)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine)}rhodium(I) perchlorate(CAS DataBase Reference)
• NIST Chemistry Reference: ((Z,Z)-cycloocta-1,5-diene){(R)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine)}rhodium(I) perchlorate(133548-33-1)
• EPA Substance Registry System: ((Z,Z)-cycloocta-1,5-diene){(R)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine)}rhodium(I) perchlorate(133548-33-1)

Safety Data

• Hazardous Substances Data: 133548-33-1(Hazardous Substances Data)

Upstream product

• 59420-05-2 bis(cyclooctadiene)rhodium(I) perchlorate 
• 133577-92-1 (R)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) 

Relevant articles and documents

Axially Dissymmetric Diphosphines in the Biphenyl Series: Synthesis of (6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) ('MeO-BIPHEP') and Analogues via an ortho-Lithiation/Iodination Ullmann-Reaction Approach

The new axially dissymmetric diphosphines (R)- and (S)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) ((R)- and (S)-5a; 'MeO-BIPHEP') and the analogues (R)- and (S)-5b and 5c have been synthesized in enantiomerically pure form.These lignands hav