1335515-69-9

Basic information

• Product Name: [(η3-CH2CMeCH2)Pd(tPhps)]Cl
• CAS NO: 1335515-69-9
• Molecular Weight: 631.475
• Mol File: 1335515-69-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(η3-CH2CMeCH2)Pd(tPhps)]Cl(CAS DataBase Reference)
• NIST Chemistry Reference: [(η3-CH2CMeCH2)Pd(tPhps)]Cl(1335515-69-9)
• EPA Substance Registry System: [(η3-CH2CMeCH2)Pd(tPhps)]Cl(1335515-69-9)

Safety Data

• Hazardous Substances Data: 1335515-69-9(Hazardous Substances Data)

Upstream product

• 1054-60-0 tetraphenyldiphosphine disulfide 

Relevant articles and documents

Synthesis and characterization of η3-Allyl palladium(II) complexes with tetraalkyldiphosphine disulfides, R2P(S)P(S)R 2 (R=Me, Et, nPr, nBu, Ph)

New allyl-palladium tetraalkyl(phenyl)diphosphine disulfide complexes, [(η3-CH2CMeCH2)Pd(tmps)]Cl, [(η3-CH2CMeCH2) Pd(teps)]Cl, [(η3-CH2CMeCH2)Pd(tpps)]Cl, [(η3-CH2CMeCH2) Pd(tbps)]Cl, [(η3-CH2CMeCH2)Pd(tPhps)]Cl, and [(R 2P(S)P(S) R2) R=Me, (tmps); Et, (teps); nPr, (tpps); nBu, (tbps); Ph, (tPhps)] have been prepared from the addition of tetraalkyl (phenyl)diphosphine disulfide to [(η3- CH2CMeCH2)Pd(μ-Cl)]2. All the complexes have been characterized by elemental analysis, Fourier-transform infrared (FT-IR), nuclear magnetic resonance (1H-NMR and 31P-{ 1H}-NMR) spectroscopy, and fast atom bombardment (FAB) mass spectrometry. The spectroscopic studies suggest that ligands are cis-chelate bidentate coordination, forming five-membered Pd-S=P-P=S palladacycles, with the η3-allyl group completing the coordination sphere. Copyright Taylor &Francis Group, LLC.