1335520-68-7Relevant academic research and scientific papers
Gold(I)-catalyzed bis-alkynylation reaction of aromatic aldehydes with alkynylsilanes
Rubial, Belen,Ballesteros, Alfredo,Gonzalez, Jose M.
supporting information, p. 3337 - 3343 (2013/12/04)
The first successful gold(I)-catalyzed reaction of aryl aldehydes with trimethyl(arylethynyl)silanes to furnish bis-alkynylated derivatives is reported. Key C-C bond-forming events involved in the catalytic cycle are analyzed. Copyright
Dialkynylation of aryl aldehydes using dialkynylboron chlorides: A transition-metal-free route to 1,4-diynes
Yao, Min-Liang,Pippin, Adam B.,Wu, Zhong-Zhi,Quinn, Michael P.,Li, Yong,Reddy, Marepally S.,Kabalka, George W.
, p. 164 - 166 (2013/01/15)
Dialkynylboron chlorides couple smoothly with aryl aldehydes at room temperature to afford 1,4-dialkynes in good to excellent yields. Dialkynylboron halides act simultaneously as Lewis acid and reactant in this coupling reaction.
Aryl aldehydes as traceless dielectrophiles in bifunctional titanocene-catalyzed propargylic C-X activations
Campos, Catherine A.,Gianino, Joseph B.,Pinkerton, David M.,Ashfeld, Brandon L.
supporting information; experimental part, p. 5680 - 5683 (2011/12/04)
The titanocene-catalyzed construction of all-carbon substituted tertiary centers directly from aromatic aldehydes is described. The starting aldehyde behaves as a traceless functionality in the formation of multiple carbon-carbon bonds through consecutive
