133578-96-8

Basic information

• Product Name: [Cu(tris(2-pyridylmethyl)amine)(H₂O)]⁽²⁺⁾
• Synonyms: [Cu(tris(2-pyridylmethyl)amine)(H₂O)]⁽²⁺⁾
• CAS NO: 133578-96-8
• Molecular Weight: 371.929
• Mol File: 133578-96-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Cu(tris(2-pyridylmethyl)amine)(H₂O)]⁽²⁺⁾(CAS DataBase Reference)
• NIST Chemistry Reference: [Cu(tris(2-pyridylmethyl)amine)(H₂O)]⁽²⁺⁾(133578-96-8)
• EPA Substance Registry System: [Cu(tris(2-pyridylmethyl)amine)(H₂O)]⁽²⁺⁾(133578-96-8)

Safety Data

• Hazardous Substances Data: 133578-96-8(Hazardous Substances Data)

Upstream product

• 114581-86-1 [Cu^I(tris(2-pyridylmethyl)amine)(CH₃CN)]²⁺ 
• 10102-43-9 nitrogen(II) oxide 

Relevant articles and documents

Molecular Structure of Nitro- and Nitrito-Copper Complexes as Reaction Intermediates in Electrochemical Reduction of Nitrite to Dinitrogen Oxide

Copper-nitrito and -nitro isomers, PF6 and PF6 (tpa = trisamine) were isolated and the molecular structures were determined by X-ray analysis. PF6 (C18H18N5O2PF6Cu) crystallizes in the monoclinic space group P21/a with a = 13.374(2), b = 14.033(2), c = 13.455(2) Angstroem, β = 119.10(1) deg, V = 2206.5(6) Angstroem3, and Z = 4. a = 16.718(3), b = 17.554(3), c = 14.785(3) Angstroem, V = 4338(1) Angstroem3, and Z = 8.Those nitrito- and nitro-complexes exist as an equilibrium mixture in solutions.Electrochemical reduction of NO2- in the presence of (ClO4)2 at -0.4 V in H2O (pH 7.0) catalytically produced N2O with concomitant evolution of a small amount of NO via the nitro and nitrito adducts.