13361-32-5

Basic information

• Product Name: Allyl cyanoacetate
• Synonyms: ALLYL CYANOACETATE;CYANOACETIC ACID ALLYL ESTER;cyano-aceticaci2-propenylester;cyano-aceticaciallylester;Acetic acid, cyano-, 2-propenyl ester;Prop-2-enylcyanoacetate;ALLYL CYANOACETATE FOR SYNTHESIS;allyl 2-cyanoacetate
• CAS NO: 13361-32-5
• Molecular Formula: C₆H₇NO₂
• Molecular Weight: 125.13
• EINECS: 236-423-4
• Product Categories: Allyl Monomers;Monomers;Polymer Science;Cyanoacetic acid esters;Hydrocyanic acid derivatives;ester series;Building Blocks;C6 to C7;Carbonyl Compounds;Chemical Synthesis;Cyanides/Nitriles;Esters;Nitrogen Compounds;Organic Building Blocks
• Mol File: 13361-32-5.mol
• Article Data: 3

Chemical Properties

• Melting Point: -40.0°C
• Boiling Point: 110 °C20 mm Hg(lit.)
• Flash Point: >230 °F
• Appearance: Liquid
• Density: 1.065 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.118mmHg at 25°C
• Refractive Index: n20/D 1.443(lit.)
• Storage Temp.: Store below +30°C.
• PKA: 3.79±0.10(Predicted)
• CAS DataBase Reference: Allyl cyanoacetate(CAS DataBase Reference)
• NIST Chemistry Reference: Allyl cyanoacetate(13361-32-5)
• EPA Substance Registry System: Allyl cyanoacetate(13361-32-5)

Safety Data

• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-28-36/37/39-45
• RIDADR: UN 3276 6.1/PG 3
• WGK Germany: 3
• RTECS: AG3690000
• HazardClass: 6.1(b)
• PackingGroup: III
• Hazardous Substances Data: 13361-32-5(Hazardous Substances Data)

Usage

Chemical Properties

Liquid

Uses

Allyl cyanoacetate is an intermediate for special adhesives. Product Data Sheet

InChI:InChI=1/C6H7NO2/c1-2-5-9-6(8)3-4-7/h2H,1,3,5H2

Upstream product

• 372-09-8 cyanoacetic acid 
• 107-18-6 allyl alcohol 
• 105-56-6 ethyl 2-cyanoacetate 

Downstream Products

• 102804-62-6 Allyl 1-cyanocyclohexanecarboxylate 
• 7324-02-9 allyl 2-cyanoacrylate 
• 454685-94-0 (S)-1-Allyl 4-ethyl 2-cyano-3-methylbutanedioate 
• 454685-94-0 (R)-1-Allyl 4-ethyl 2-cyano-3-methylbutanedioate 
• 6731-59-5 2-benzyl-2-cyano-pent-4-enoic acid ethyl ester 
• 922490-95-7 2-benzyl-2-cyano-pent-4-ynoic acid ethyl ester 
• 1030620-13-3 2-cyano-3-phenylpropionic acid allyl ester 
• 1030620-40-6 2-benzyl-2-cyanopent-4-enoic acid allyl ester 
• 1030620-41-7 2-benzyl-2-cyanopent-4-ynoic acid allyl ester 
• 1196977-37-3 C₁₂H₁₅NO₃ 
• 3695-84-9 methyl benzylidenecyanoacetate 
• 75265-77-9 allyl 2-cyano-2-cyclohexylideneacetate 

Relevant articles and documents

IMINIUM SALTS AND METHODS OF PREPARING ELECTRON DEFICIENT OLEFINS USING SUCH NOVEL IMINIUM SALTS

This invention relates to novel iminium salts, which may be in the form of ionic liquids, and a process for producing electron deficient olefins, such as 2-cyanoacrylates, using such an iminium salt, for instance in the form of an ionic liquid.

ESTERIFICATION OF CARBOXYLIC ACIDS WITH ALLYL ALCOHOL

The kinetics of the esterification of substituted carboxylic acids with allyl alcohol were studied.The reaction is of first order in the catalyst and in the substrate, and the equilibrium under the investigated conditions is shifted toward the formation of the ester.The observed enthalpy of activation does not depend on the substituent, and the difference in the reactivities of the investigated compounds is determined entirely by the entropy component of the free energy.