133618-94-7

Basic information

• Product Name: 2'-Methylsulfanyl-[1,1']binaphthalenyl-2-thiol
• CAS NO: 133618-94-7
• Molecular Weight: 332.49
• Mol File: 133618-94-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2'-Methylsulfanyl-[1,1']binaphthalenyl-2-thiol(CAS DataBase Reference)
• NIST Chemistry Reference: 2'-Methylsulfanyl-[1,1']binaphthalenyl-2-thiol(133618-94-7)
• EPA Substance Registry System: 2'-Methylsulfanyl-[1,1']binaphthalenyl-2-thiol(133618-94-7)

Safety Data

• Hazardous Substances Data: 133618-94-7(Hazardous Substances Data)

Upstream product

• 124414-28-4 (2,2'-Dimethylthio)<1,1'-binaphthalene> 

Relevant articles and documents

Enantioselective oxidation of thioethers. A route to the resolution of -2,2'-dithiol

A route to the resolution of racemic -2,2'-dithiol 2 is described, involving the transformation of 2 into a series of dithioethers.The latter are subjected to asymmetric oxidation to monosulfoxides by a procedure developed in our laboratory.For some of the thioethers examined the oxidation is highly diastereo- and/or enantioselective.The resolved 2 is then obtained from the optically pure monosulfoxides either by oxidation to the bis-sulfoxides followed by a Pummerer reaction or by a deoxygenation to the dithioether and subsequent reduction.In both cases enantiomerically pure 2 (e.e. > 98percent) was obtained.Keywords: enantioselective oxidation / optical resolution / thioethers / -2,2'-dithiol