133634-83-0Relevant articles and documents
Synthesis of methylene exoglycals using a modified Julia olefination
Gueyrard, David,Haddoub, Rose,Salem, Amine,Bacar, Nassib Said,Goekjian, Peter G.
, p. 520 - 522 (2005)
A new route to exomethylene sugars is reported. The use of a two-step coupling-elimination procedure allows successful Julia olefination of sugar-derived lactones. Georg Thieme Verlag Stuttgart.
METHYLENATION OF ALDONOLACTONES
Csuk, Rene,Glaenzer, Brigitte I.
, p. 1655 - 1664 (2007/10/02)
Convenient access to carbohydrates possessing an exo-methylene group adjacent to the ring oxygen at C-1 can be achieved by direct methylenation of aldonolactones with dicyclopentadienyldimethyltitanium.