133696-51-2

Upstream product

• 768-33-2 phenyldimethylsilyl chloride 
• 3839-31-4 dimethyl(phenyl)silyllithium 
• 133618-96-9 (E)-1-(phenyldimethylsilyl)-4-(benzyloxy)-but-2-en-1-ol 
• 69152-87-0 4-benzyloxycrotonaldehyde 
• 156568-06-8 (E)-4-(Benzyloxy)-1-(dimethylphenylsilyl)-1-oxobut-2-ene 
• 133619-06-4 (1R)-1-(1-dimethylphenylsilyl-4-benzyloxy-2-butene) (2R)-2-O-acetyl-2-phenylacetate 

Downstream Products

• 129921-63-7 (R)-(E)-1-(Acetyloxy)-4-(benzyloxy)-1-(dimethylphenylsilyl)-2-butene 
• 156568-09-1 (3S,4R,5R)-6-(Benzyloxy)-4-(methoxymethoxy)hex-1-ene-3,5-diol 
• 156568-11-5 (4R,5R,6S)-4-((Benzyloxy)methyl)-5-(methoxymethoxy)-6-vinyl-1,3-dioxane 
• 156618-58-5 (2S,3R)-4-(Benzyloxy)-3-((tert-butyldimethylsilyl)oxy)-2-(methoxymethoxy)-1-butanal 
• 156618-57-4 (2S,3R)-4-(Benzyloxy)-3-((tert-butyldimethylsilyl)oxy)-1-(dimethylphenylsilyl)-2-(methoxymethoxy)-1-oxobutane 
• 156568-17-1 (1R,2S,3R)-4-(Benzyloxy)-3-((tert-butyldimethylsilyl)oxy)-1-(dimethylphenylsilyl)-2-(methoxymethoxy)-1-butanol 
• 156568-16-0 (1R,2S,3R)-1-(Acetyloxy)-4-(benzyloxy)-3-((tert-butyldimethylsilyl)oxy)-1-(dimethylphenylsilyl)-2-butanol 
• 1027558-61-7 (1R,2S,3R)-1-(Acetyloxy)-4-(benzyloxy)-3-((tert-butyldimethylsilyl)oxy)-1-(dimethylphenylsilyl)-2-(methoxymethoxy)butane 
• 156568-08-0 (3S,4R,5R)-3,4-syn-6-(Benzyloxy)-5-((tert-butyldimethylsilyl)oxy)-4-(methoxymethoxy)hex-1-en-3-ol 
• 156618-56-3 (1R,2S,3R)-1,2-anti-1-(Acetyloxy)-4-(benzyloxy)-1-(dimethylphenylsilyl)butane-2,3-diol 
• 129921-55-7 Acetic acid (E)-(R)-1-benzyloxymethyl-3-(dimethyl-phenyl-silanyl)-allyl ester 

Relevant academic research and scientific papers

Studies Directed toward the Synthesis of (+)-Sesbanimide A: Construction of the AB-Ring System (A Formal Total Synthesis)

Complete details of a study leading to the asymmetric synthesis of the AB-ring system of (+)-sesbanimide A (1), a potent cytotoxic agent belonging to the class of sesbania alkaloids, are described.Key features of the synthesis include (a) the stereoselect

Synthesis, resolution and absolute stereochemical assignment of C1-oxygenated allylsilanes and C3-oxygenated vinylsilanes

(R)-O-acetyl mandelic acid has been utilized for the development of a procedure for resolution and absolute stereochemical assignment of C1-oxygenated E-crotylsilanes 1a-c. The procedure is enhanced further by an efficient boron trifluoride etherate catal