133696-53-4

Upstream product

• 133619-05-3 (1S)-1-(1-dimethylphenylsilyl-2-butene) (2R)-2-hydroxy-2-phenylacetate 
• 96720-38-6 (E)-1-(phenyldimethylsilyl)-2-buten-1-ol 
• 768-33-2 phenyldimethylsilyl chloride 
• 3839-31-4 dimethyl(phenyl)silyllithium 
• 133619-02-0 1-(1-dimethylphenylsilyl-2-butene) (2R)-2-O-acetyl-2-phenylacetate 

Downstream Products

• 129921-58-0 Acetic acid (E)-(S)-1-(dimethyl-phenyl-silanyl)-but-2-enyl ester 
• 129921-59-1 Methoxy-acetic acid (E)-(S)-1-(dimethyl-phenyl-silanyl)-but-2-enyl ester 
• 129921-52-4 Azido-acetic acid (E)-(R)-3-(dimethyl-phenyl-silanyl)-1-methyl-allyl ester 
• 129921-61-5 Azido-acetic acid (E)-(S)-1-(dimethyl-phenyl-silanyl)-but-2-enyl ester 
• 129921-49-9 Methoxy-acetic acid (E)-(R)-3-(dimethyl-phenyl-silanyl)-1-methyl-allyl ester 
• 129921-50-2 Methoxy-acetic acid (E)-(S)-3-(dimethyl-phenyl-silanyl)-1-methyl-allyl ester 
• 129921-47-7 (R)-(E)-3-[1-(dimethylphenylsilyl)-1-butenyl] acetate 
• 129921-48-8 Acetic acid (E)-(S)-3-(dimethyl-phenyl-silanyl)-1-methyl-allyl ester 
• 129921-51-3 Chloro-acetic acid (E)-(R)-3-(dimethyl-phenyl-silanyl)-1-methyl-allyl ester 
• 129921-60-4 Chloro-acetic acid (E)-(S)-1-(dimethyl-phenyl-silanyl)-but-2-enyl ester 

Relevant academic research and scientific papers

Kinetic Resolution of α-Silyl-Substituted Allylboronate Esters via Chemo- and Stereoselective Allylboration of Aldehydes

We describe the kinetic resolution of α-silyl-substituted allylboronate esters via chiral phosphoric acid-catalyzed chemo-, diastereo- and enantioselective allylboration of aldehydes. This process provides two synthetically versatile enantioenriched compo

Mechanistic studies of the allylic rearrangements of α-silyloxy allylic silanes to silyloxy vinylic silanes

(Chemical Equation Presented) Mechanistic evidence suggests that the Lewis acid-promoted allylic rearrangement of α-silyloxy allylic silanes proceeds along an ionic reaction pathway involving a contact ion pair. The driving force for this transformation i

Synthesis, resolution and absolute stereochemical assignment of C1-oxygenated allylsilanes and C3-oxygenated vinylsilanes

(R)-O-acetyl mandelic acid has been utilized for the development of a procedure for resolution and absolute stereochemical assignment of C1-oxygenated E-crotylsilanes 1a-c. The procedure is enhanced further by an efficient boron trifluoride etherate catal