133705-73-4Relevant academic research and scientific papers
Free radical and palladium-catalysed hydrostannation of allenes: a comparison
Mitchell, Terence N.,Schneider, Ulrich
, p. 195 - 199 (2007/10/02)
While free radical hydrostannation of monosubstituted allenes with Me3SnH affords mixtures of varying composition, cyclohexylidene allene is attacked by the stannyl radical preferentially at the central carbon atom.In contrast, palladium-catalysed hydrostannation involves a regioselective attachment of the organotin moiety to the less highly substituted terminal carbon atom of the allene framework.
